Efficient synthesis of dimethyl carbonate via transesterification of ethylene carbonate over a new mesoporous ceria catalyst
β Scribed by Xu, Jie; Long, Kai-Zhou; Wu, Fei; Xue, Bing; Li, Yong-Xin; Cao, Yong
- Book ID
- 125826381
- Publisher
- Elsevier Science
- Year
- 2014
- Tongue
- English
- Weight
- 882 KB
- Volume
- 484
- Category
- Article
- ISSN
- 0926-860X
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π SIMILAR VOLUMES
## Abstract **Basic instinct**: Basic aluminates derived from the activation of Naβ and Kβdawsonites are highly active and reusable catalysts for the transesterification of ethylene carbonate and methanol to dimethyl carbonate. The product is obtained in about 65β% yield in 6β h even when the reacti
## Abstract Transesterification of ethylene carbonate (EC) with methanol (MeOH) was studied in a slurry reactor using various homogeneous and heterogeneous, acidic as well as basic, catalysts. Among all catalysts studied, the weakly basic anionβexchange resin Amberlyst Aβ21 gave more than 95% selec