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Efficient Synthesis of Cyclic Carbonates by Mg II /Phosphine-Catalyzed Coupling Reactions of Carbon Dioxide and Epoxides

✍ Scribed by Ren, Yiping; Shim, Jae-Jin

Book ID
120021002
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
502 KB
Volume
5
Category
Article
ISSN
1867-3880

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## Abstract The heterobimetallic complexes [(Ξ·^5^‐C~5~H~5~)Ru(CO)(μ‐dppm)Mn(CO)~4~] and [(Ξ·^5^‐C~5~Me~5~)Ru(μ‐dppm)(μ‐CO)~2~Mn(CO)~3~] (dppm= bis‐diphenylphosphinomethane) have been prepared by reacting the hydridic complexes [(Ξ·^5^‐C~5~H~5~)Ru(dppm)H] and [(Ξ·^5^‐C~5~Me~5~)Ru(dppm)H], respectively,