Efficient synthesis of carbazoles via PtCl2-catalyzed RT cyclization of 1-(indol-2-yl)-2,3-allenols: scope and mechanism
✍ Scribed by Kong, Wangqing; Fu, Chunling; Ma, Shengming
- Book ID
- 118153511
- Publisher
- Royal Society of Chemistry
- Year
- 2012
- Tongue
- English
- Weight
- 447 KB
- Volume
- 10
- Category
- Article
- ISSN
- 1477-0520
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract Transition‐metal‐catalyzed dimeric coupling–cyclization reactions of two different 2,3‐allenols afforded 4‐(1′,3′‐dien‐2′‐yl)‐2,5‐dihydrofuran derivatives **3**. 2‐Substituted 2,3‐allenols **1** cyclized to form the 2,5‐dihydrofuran ring, whereas the 2‐unsubstituted 2,3‐allenols **2** p
4-(2%-Alkenyl)-2,5-dihydrofurans can be efficiently synthesized via the PdCl 2 -catalyzed coupling-cyclization of allylic halides with 2,3-allenols in DMA at rt in moderate to good yields. The regioselectivity is different from that of the Pd(0)-catalyzed coupling-cyclization of organic halides with