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Efficient Synthesis of Calix[6]tmpa: A New Calix[6]azacryptand with Unique Conformational and Host–Guest Properties

✍ Scribed by Xianshun Zeng; David Coquière; Aurélie Alenda; Eva Garrier; Thierry Prangé; Yun Li; Olivia Reinaud; Ivan Jabin


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
424 KB
Volume
12
Category
Article
ISSN
0947-6539

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Synthesis and host–guest properties of a
✍ Jean-Alexandre Richard; Marc Pamart; Nicolas Hucher; Ivan Jabin 📂 Article 📅 2008 🏛 Elsevier Science 🌐 French ⚖ 465 KB

The straightforward synthesis of a C s symmetrical calix[6]arene possessing carboxylic acid groups as well as an ammonium arm is described. This calixarene can encapsulate ammonium ions through a highly selective recognition process thanks to the presence of an internal ion-paired cap that preorgani