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Efficient synthesis of AB ring core of luotonin A derivatives: (2-chloroquinolin-3-yl)methanamine

✍ Scribed by Selvaraj Mohana Roopan; F. Nawaz Khan; Jong Sung Jin

Book ID: 106518075
Publisher: Springer Netherlands
Year: 2011
Tongue: English
Weight: 591 KB
Volume: 38
Category: Article
ISSN: 0922-6168
DOI: 10.1007/s11164-011-0361-4

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## Abstract Reactions of (__N__‐isocyanimino) triphenylphosphorane with 2‐oxopropylbenzoate (or acetate) in the presence of aromatic carboxylic acids and primary amines proceed smoothly at room temperature and in neutral conditions to afford sterically congested 1,3,4‐oxadiazole derivatives in high