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Efficient syntheses of trans-(+)-laurediol from carbohydrate precursors

✍ Scribed by Rajendrakumar Reddy Gadikota; Adam I. Keller; Christopher S. Callam; Todd L. Lowary

Book ID
104359689
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
163 KB
Volume
14
Category
Article
ISSN
0957-4166

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✦ Synopsis

Two routes for the synthesis of the marine natural product trans-laurediol 6 are described. In the first approach 6 is obtained in ten steps and 21% overall yield from monoacetone D-glucose. The second route provides the target in eleven steps and 13% yield from D-mannose. Both routes are more efficient, both in terms of number of steps and overall yield, than previously reported syntheses.

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