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Efficient Syntheses and Resolutions of Inherently Chiral Calix[4]quinolines in the Cone and Partial-Cone Conformation

✍ Scribed by Miao, Ru; Zheng, Qi-Yu; Chen, Chuan-Feng; Huang, Zhi-Tang

Book ID
127284839
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
229 KB
Volume
70
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

Synthesis and Optical Resolution of a Se
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## Abstract A series of inherently chiral calix[4]arenes with cone and partial cone conformations and with crown ether moieties of variable size have been readily synthesized. By taking advantage of the carboxy appendage on the lower rim, these were condensed with the chiral auxiliary (__S__)‐BINOL

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Two calix[4] arene derivatives, in the partial cone conformation, with sulfur-containing functionalities, were tested as neutral carrier ionophores in potentiometric silver-selective electrodes of conventional membrane and membrane-coated glassy carbon electrode types. Comparison with a calix[4]are