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Efficient Ruthenium-Catalyzed Transfer Hydrogenation/Hydrogenation of 1,3-Cycloalkanediones to 1,3-Cycloalkanediols Using Microwave Heating

✍ Scribed by Leijondahl, Karin; Fransson, Ann-Britt L.; Bäckvall, Jan-E.


Book ID
118006482
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
128 KB
Volume
71
Category
Article
ISSN
0022-3263

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Ruthenium-catalyzed asymmetric reduction
✍ Janine Cossy; Florence Eustache; Peter I Dalko 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 59 KB

1,3-Diketones were reduced to 1,3-diols by using RuCl[N-(tosyl)-1,2-(diphenylethylenediamine) (h 6 -arene)] in the presence of formic acid and triethylamine. 1,3-Diols were obtained in good chemical yields and with high ee when symmetrical diketones were reduced.