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Efficient Ruthenium Carbenoid-Catalyzed Cross-Metathesis of Allyl Halides with Olefins

✍ Scribed by Liu, Bingcan; Das, Sanjoy K.; Roy, René


Book ID
120162959
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
57 KB
Volume
4
Category
Article
ISSN
1523-7060

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Competing ruthenium catalyzed metathesis
✍ John C Sworen; James H Pawlow; Will Case; John Lever; Kenneth B Wagener 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 129 KB

Metathesis condensation and isomerization reactions of allylic compounds were examined using Grubbs' second-generation ruthenium catalyst [Ru \* ]. Allyl alcohol and allyl cyanide undergo metathesis condensation releasing ethylene, with conversions being the highest reported for these substrates. Ho