✦ LIBER ✦

Efficient rhodium and iridium-catalysed asymmetric transfer hydrogenation using water-soluble aminosulfonamide ligands

✍ Scribed by Tim Thorpe; John Blacker; Stephen M Brown; Christian Bubert; John Crosby; Steven Fitzjohn; James P Muxworthy; Jonathan M.J Williams

Book ID: 104230690
Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 62 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)00624-4

No coin nor oath required. For personal study only.

✦ Synopsis

A range of aromatic ketones was reduced asymmetrically under transfer hydrogenation conditions using enantiomerically pure catalysts derived from water-soluble diamine ligands and [Cp*MCl 2 ] 2 (Cp*=pentamethylcyclopentadienyl, M=Rh, Ir). High catalytic activity and enantioselectivity were observed in systems containing up to 51% water.

📜 SIMILAR VOLUMES

ChemInform Abstract: Efficient Rhodium-

ChemInform Abstract: Efficient Rhodium- and Iridium-Catalyzed Asymmetric Transfer Hydrogenation Using Water-Soluble Aminosulfonamide Ligands.

✍ Tim Thorpe; John Blacker; Stephen M. Brown; Christian Bubert; John Crosby; Steve 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB 👁 2 views

Water-soluble chiral aminosulfonamides a

Water-soluble chiral aminosulfonamides as ligands for ruthenium(II)-catalyzed asymmetric transfer hydrogenation

✍ Zhongqiang Zhou; Yong Sun 📂 Article 📅 2009 🏛 Elsevier Science 🌐 English ⚖ 258 KB

Synthesis of water-soluble aminosulfonam

Synthesis of water-soluble aminosulfonamide ligands and their application in enantioselective transfer hydrogenation

✍ Christian Bubert; John Blacker; Stephen M Brown; John Crosby; Steven Fitzjohn; J 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 85 KB

Water-soluble analogues of Noyori's (1S,2S)-N-(p-tolylsulfonyl)-1,2-diphenylethylenediamine and Knochel's (1R,2R)-N-(p-tolylsulfonyl)-1,2-diaminocyclohexane, containing an additional sulfonic acid group, have been synthesised. The ruthenium catalysed reduction of aromatic ketones using enantiomerica

Efficient Iridium and Rhodium-Catalyzed

Efficient Iridium and Rhodium-Catalyzed Asymmetric Transfer Hydrogenation Using 9-Amino(9-deoxy) cinchona Alkaloids as Chiral Ligands.

✍ Wei He; Peng Liu; Bang Le Zhang; Xiao Li Sun; Sheng Yong Zhang 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 26 KB 👁 1 views

Efficient iridium and rhodium-catalyzed

Efficient iridium and rhodium-catalyzed asymmetric transfer hydrogenation using 9-amino(9-deoxy) cinchona alkaloids as chiral ligands

✍ Wei He; Peng Liu; Bang Le Zhang; Xiao Li Sun; Sheng Yong Zhang 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 133 KB 👁 2 views

ChemInform Abstract: Synthesis of Water-

ChemInform Abstract: Synthesis of Water-Soluble Aminosulfonamide Ligands and Their Application in Enantioselective Transfer Hydrogenation.

✍ Christian Bubert; John Blacker; Stephen M. Brown; John Crosby; Steven Fitzjohn; 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v