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Efficient preparation of enol carbonates by selective O-acylation of ketone sodium enolates generated in the presence of TMEDA

✍ Scribed by Laurence M. Harwood; Yoram Houminer; Ajith Manage; Jeffrey I. Seeman


Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
230 KB
Volume
35
Category
Article
ISSN
0040-4039

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Enolate-Phosphane Ligands Providing a To
✍ Bernard Demerseman; LoΓ―c Toupet πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 203 KB πŸ‘ 2 views

## Abstract The deprotonation under basic conditions of the keto‐phosphane ligand in complexes {Ru(Cp)[Ξ·^1^‐__P__‐Ph~2~PCH~2~C(=O)__t__Bu](PPh~3~)(L)}[PF~6~] (L = CO or PMe~3~) that arise from the addition of L to {Ru(Cp)[Ξ·^2^‐__P__,__O__‐Ph~2~PCH~2~C(__t__Bu)=O](PPh~3~)}[PF~6~] generates {Ru^+^(Cp