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Efficient oxygenation of hydrocarbons with tetrabutylammonium monopersulfate catalyzed by manganese meso-tetraphenylporphyrin in the presence of imidazole

โœ Scribed by Daryoush Mohajer; Abdolreza Rezaeifard

Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
118 KB
Volume
43
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Oxidation of hydrocarbons, into their corresponding epoxide, alcohol and/or ketone, was achieved with tetrabutylammonium monopersulfate in the presence of manganese(III) meso-tetraphenylporphyrin catalyst and axial imidazole ligand in CH 2 Cl 2 in low to very high yields (13-100%) and good to excellent selectivities (73-100%) in less than 5 min at room temperature ( 25ยฐC).

๐Ÿ“œ SIMILAR VOLUMES

Efficient olefin epoxidation with tetrab
Efficient olefin epoxidation with tetrabutylammonium periodate catalyzed by manganese porphyrin in the presence of imidazole
โœ Daryoush Mohajer; Shahram Tangestaninejad ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 244 KB

## Epoxidation of various olefins is achieved by Mm-n-butylammarium periodate in the. preamce of manganese (III) meso-tetraphenylporphyrin and imidamle in CH$l,. with high selectivity and yield under mild conditions. The modeling of cytochrome P-450 class of enzymes with synthetic metalloporphyrin