Efficient Oxidation of Adamantanes by Sodium Nitrite with Molecular Oxygen in Trifluoroacetic Acid.
โ Scribed by Osamu Onomura; Yutaka Yamamoto; Noriaki Moriyama; Fumiaki Iwasaki; Yoshihiro Matsumura
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 17 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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๐ SIMILAR VOLUMES
Oxidative carbon-carbon bond cleavage of N-alkoxycarbonylated cyclic amines was accomplished by NaNO 2 in TFA to afford x-amino carboxylic acid in high yield. Optically active 3-hydroxypiperidine derivatives and 3-pipecolinate were converted to enantiomerically pure (R)-4-amino-3-hydroxybutanoic aci
## Abstract magnified image An inexpensive catalytic system consisting of vanadyl sulfate and sodium nitrite was developed for the oxidation of benzylic alcohols with molecular oxygen under mild conditions. Benzyl alcohols with various substitutions were efficiently converted to their correspondin