Dibenzyltin bis(2-ethylhexanoate) 1 (4-Y-C 6 H 4 CH 2 ) 2 Sn(OC(O)R 1 ) 2 [Y = H, 1a; MeO, 1b; Cl, 1c; Me, 1d; and R 1 = MeCH 2 CH 2 CH 2- CH(Et)-] were synthesized either from the reaction of corresponding dibenzyltin dichlorides with silver 2-ethylhexanoate or from the reaction of dibenzyltin oxides with 2-ethylhexanoic acid. Compound 1a was further utilized as a catalyst for the reaction of mono-and diisocyanates [PhNCO, CH 3 C 6 H 3 -2,4-(NCO) 2 and OCN(CH 2 ) 6 NCO] with alcohols (primary, secondary, tertiary, cyclohexcyl, alkyl, allyl, benzyl and aryl) leading to the formation of the corresponding urethanes. The catalytic efficiencies of 1 vis-a `-vis industrially known organotin catalysts have been determined through kinetic studies for the reaction of PhNCO and n-BuOH at various temperatures. Compounds 1a, 1c and 1d show higher efficiency than dibutyltin bis(2ethylhexanoate). FTIR studies further provide mechanistic insights into the catalytic cycle, which comprises pre-coordination of isocyanate to tin(IV), formation of stannyl carbamate and generation of dibenzyl(alkoxy)carboxylate as the active catalyst.