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Efficient Microwave-Assisted Pd-Catalyzed Hydroxylation of Aryl Chlorides in the Presence of Carbonate

โœ Scribed by Yu, Chao-Wu; Chen, Grace S.; Huang, Chen-Wei; Chern, Ji-Wang

Book ID
120233907
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
296 KB
Volume
14
Category
Article
ISSN
1523-7060

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Simple and efficient procedures for the Pd-catalyzed cross-coupling reaction of aryl chlorides and dimethylamine are described. At room temperature with a strong base, t-BuXPhos is employed as the supporting ligand; at 110 ยฐC with a weak base, XPhos is employed as the supporting ligand. In each of t