𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Efficient Intramolecular Hydroarylation Catalysed by BiIII Triflate

✍ Scribed by Bastien Cacciuttolo; Sophie Poulain-Martini; Elisabet Duñach

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
494 KB
Volume
2011
Category
Article
ISSN
1434-193X

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Non‐activated aromatic compounds bearing unsaturated side‐chains afford tetralin and benzosuberan derivatives in good yields in an atom‐economic, environmentally friendly process catalysed by bismuth(III) trifluromethanesulfonate.

📜 SIMILAR VOLUMES

Efficient Intramolecular Hydroalkoxylati
Efficient Intramolecular Hydroalkoxylation of Unactivated Alkenols Mediated by Recyclable Lanthanide Triflate Ionic Liquids: Scope and Mechanism
✍ Alma Dzudza; Tobin J. Marks 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 683 KB

## Abstract Lanthanide triflate complexes of the type [Ln(OTf)~3~] (Ln=La, Sm, Nd, Yb, Lu) serve as effective, recyclable catalysts for the rapid intramolecular hydroalkoxylation (HO)/cyclization of primary/secondary and aliphatic/aromatic hydroxyalkenes in imidazolium‐based room‐temperature ionic