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Efficient Intramolecular Hydroalkoxylation/Cyclization of Unactivated Alkenols Mediated by Lanthanide Triflate Ionic Liquids

✍ Scribed by Dzudza, Alma; Marks, Tobin J.


Book ID
127045505
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
115 KB
Volume
11
Category
Article
ISSN
1523-7060

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Efficient Intramolecular Hydroalkoxylati
✍ Alma Dzudza; Tobin J. Marks 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 683 KB

## Abstract Lanthanide triflate complexes of the type [Ln(OTf)~3~] (Ln=La, Sm, Nd, Yb, Lu) serve as effective, recyclable catalysts for the rapid intramolecular hydroalkoxylation (HO)/cyclization of primary/secondary and aliphatic/aromatic hydroxyalkenes in imidazolium‐based room‐temperature ionic