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Efficient homocoupling reactions of halide compounds catalyzed by manganese (II) chloride

✍ Scribed by Yu Yuan; Yubo Bian

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
107 KB
Volume
22
Category
Article
ISSN
0268-2605

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✦ Synopsis

Abstract

A new efficient homocoupling reaction was reported in one pot by a combination of metallic magnesium and a catalytic amount of manganese (II) chloride. Various aromatic and alkyl halides underwent homocoupling smoothly, affording the corresponding symmetrical homocoupling compounds in moderate to good yields. The readily available MnCl~2~, the mild reaction conditions and the operational simplicity and practicability allow for an easy and practical procedure for the purpose of carbonο£Ώcarbon bond formation. Copyright Β© 2007 John Wiley & Sons, Ltd.

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