𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Efficient Generation of ortho-Quinone Methide: Application to the Biomimetic Syntheses of (±)-Schefflone and Tocopherol Trimers

✍ Scribed by Liao, Daohong; Li, Houhua; Lei, Xiaoguang


Book ID
115451997
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
871 KB
Volume
14
Category
Article
ISSN
1523-7060

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


o-Quinone methide based approach to isof
✍ Santosh J. Gharpure; A.M. Sathiyanarayanan; Prasad Jonnalagadda 📂 Article 📅 2008 🏛 Elsevier Science 🌐 French ⚖ 141 KB

A concise strategy is developed for the synthesis of isoflavans employing a Diels-Alder reaction between o-quinone methides and aryl-substituted enol ethers followed by reductive cleavage of the acetal group. The method is extended towards the total syntheses of equol, 3 0 -hydroxyequol and vestitol