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Efficient Epoxidation of Electron-Deficient Olefins with a Cationic Manganese Complex.

โœ Scribed by Andrew Murphy; Geraud Dubois; T. D. P. Stack

Publisher
John Wiley and Sons
Year
2003
Weight
135 KB
Volume
34
Category
Article
ISSN
0931-7597

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Efficient Homogeneous Hydrosilylation of
Efficient Homogeneous Hydrosilylation of Olefins by Use of Complexes of Pt0 with Selected Electron-Deficient Olefins as Ligands
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A family of complexes of general formula [Pt(h 2 -Ol E ){(h 4 -CH 2 CHSiMe 2 ) 2 O}], where Ol E is a di-, tri-or tetrasubstituted electron-deficient olefin such as fumaronitrile, diethylfumarate, tetracyanoethylene, ethylenetetracarboxylate, a naphthoquinone or dihydronaphthoquinone, were synthesis