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Efficient Energy Transfer in Supramolecular, Hydrogen-Bonded Polypyridylruthenium-Osmium Complexes

✍ Scribed by Sven Rau; Bernhard Schäfer; Sebastian Schebesta; André Grüßing; Wolfgang Poppitz; Dirk Walther; Marco Duati; Wesley R. Browne; Johannes G. Vos

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
110 KB
Volume
2003
Category
Article
ISSN
1434-1948

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✍ Arnulf Staib; James T. Hynes 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 817 KB

A theory for vibrational predissociation of hydrogen-bonded OH...0 complexes via OH stretch-00 stretch energy transfer is constructed, motivated by a recent experiment on vibrational predissociation of hydrogen-bonded ethanol dimer in solution. The theory employs a vibrationally adiabatic perspectiv