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Efficient enantioselective synthesis of a β-hydroxyepoxide building block for the construction of macrocyclic natural products

✍ Scribed by Ulrich Schlede; Marc Nazaré; Herbert Waldmann

Book ID
108386501
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
168 KB
Volume
39
Category
Article
ISSN
0040-4039

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## Abstract The synthesis of ethyl (2__E__, 4__E__, 8__R__)‐8‐methyl‐10‐[(2__H__‐tetrahydropyran‐2‐yl)oxy]‐2,4‐decadienoate (**11**), methyl (2__E__, 8__R__)‐8‐methyl‐10‐[(2__H__‐tetrahydropyran‐2‐yl)oxy]‐2‐decenoate (**16**), synthons for the construction of the macrocyclic moieties of the cytocha