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Efficient Electrophilic and Nucleophilic Epoxidations Utilizing a Sulfonylperoxy Radical and Peroxysulfate Species.

✍ Scribed by Min Young Park; Seung Gak Yang; Yong Hae Kim


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
33
Category
Article
ISSN
0931-7597

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Efficient electrophilic and nucleophilic
✍ Min Young Park; Seung Gak Yang; Yong Hae Kim 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 174 KB

## Abstract Reaction of superoxide anion radical (O~2~^−·^) with o‐nitrobenzenesulfonyl chloride yields a o‐nitrobenzenesulfonyl peroxy radical with strong oxidizing ability, which is capable of oxidizing aryl methylene moieties to aryl ketones and relatively electron‐rich alkenes regioselectively