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Efficient Access to Perfluoroalkylated Aryl Compounds by Heck Reaction

✍ Scribed by Sylvain Darses; Mathieu Pucheault; Jean-Pierre Genêt

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
380 KB
Volume
2001
Category
Article
ISSN
1434-193X

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✦ Synopsis

Efficient introduction of perfluorinated tails onto aromatic rings has been achieved by Heck reaction between perfluoroalkenes and arenediazonium salts, catalysed by palladium acetate. Subsequent transition metal catalysed hydrogenation of the double bond afforded a large variety of aromatic compounds bearing an affinity for fluorous solvents.

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