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Efficiency of chelated iron compounds as catalysts for the Haber-Weiss reaction

✍ Scribed by Sutton, Harry C.


Book ID
122506770
Publisher
Elsevier Science
Year
1985
Weight
673 KB
Volume
1
Category
Article
ISSN
0748-5514

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Unusual efficiency of a non-heme iron co
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The non-heme iron complex, Fe(TPAA = tris-[N-(2-pyridylmethyl)-2-aminoethyl]amine)(ClO 4 ) 2 , is a bad catalyst for the epoxidation of alkenes such as cyclooctene, cyclohexene and cis-stilbene and for the hydroxylation of alkanes such as adamantane by H 2 O 2 , when compared to the iron porphyrin F