## Abstract The synthesis of 1‐fluoro‐4,4‐di‐hydroxymethyl‐pentane (I) and its dicarbamate (II) is described. (I) is obtained by classical alkylation of methylmalonic ester with 1‐ bromo‐3‐fluoro‐propane and subsequent reduction with LiAlH~4~, of the fluorinated diester obtained. Treated with phosg
✦ LIBER ✦
Effets des substituants sur la conformation du cycle γ-lactonique: I. Dérivés de la γ-butyrolactone
✍ Scribed by Jean-Pierre Lere-Porte; Jacqueline Galsomias; Jean Petrissans; Marie-Claire Brianso
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 992 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0022-2860
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The i.r. stretching frequencies of the carbonyl group and the chemical shift of the ethylenic proton in three series of aJi-unsaturated ketones, 3-substituted-5,5-dimethyl-2-cyclohexen-1-ones s-trans p-substituted-4-aryl-3-buten-2-ones and p-substituted-3-aryl-5,5-dimethyl-2-cyclohexen-l-ones, have