Delayed and prompt 5uorescekce spectra and delayed fluokscenctt decay data far ~0'5-106 M/M crystals of anfltracene in phenanthrene are report&d\* It is shown that these data indicate that a heterogeneous (host-dopant) annihiiation process takes place which produces the excited singlet state of -tie
Effects of traps on triplet-triplet annihilation in phenanthrene crystals
β Scribed by Nobuko I. Wakayama
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 324 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The temperature dependences of delayed and prompt fluorescence spectra for anthracene doped phenanthrene crystals (2 X lo* and less than lo6 M/M) have been studied :n the temperature range 77-293 K. The experimental results indicate that a shallow trap the depth of which is 250 cm-* competes with the deep anthracene trap in triplet excitation energy transfer from the host. The concentration of the shallow trap is estimated to be ca. 2.5 X 10" M/hi.
π SIMILAR VOLUMES
The rate constants of triplet-triplet annihilation were measured in anthracene single crystals with various degrees of damage. It was found that, as with the singleexcitonic triplet decay rate, the doubleexcitonic triplet decay rate is severely affected by the presence of crystal defects. The experi
The effects of temperature and solvent on tile magnetic field dependence of delayed monomer and excimer fiuorescence of ~OXIX&CS in solution are disc- The field effect data elucidate the mecbnism of excimer formation in triplet-triPlet a3lialSticn.
## Mutual annihilation of triplet excitons in Pt-phthalocyanine single crystal at 4.2 K has been studiti under magnetic fieIds of up to 100 kG through the measurement of the phosphorescence decay by Q-switched ruby laser excitation\_ The maximum annihilation rate y which is larger than that of zer
The magnetic field modulation of the delayed fluorescence and of the photoconduction of 9,lO-dichloroanthracene was measured. The ener,? transfer from triplet exciton to trapped positive holes is shown to be responsible for the photodetrapping.