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Effects of the conformational rearrangement of the (np3)M fragment in the course of the reaction between (np3)MH hydrides [M = Co, Rh; np3 = N(CH2CH2PPh2)3] and carbon disulfide

✍ Scribed by Bianchini, Claudio.; Masi, Dante.; Mealli, Carlo.; Meli, Andrea.; Sabat, Michal.


Book ID
126853512
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
775 KB
Volume
4
Category
Article
ISSN
0276-7333

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## Abstract Thermolysis of Ru(IMes)(dppp)(CO)H~2~ (1, IMes=1,3‐dimesityl‐1,3‐dihydro‐2__H__‐imidazol‐2‐ylidene; dppp=Ph~2~PCH~2~CH~2~CH~2~PPh~2~) in the presence of trimethylvinylsilane yields Ru(IMes')(dppp)(CO)H (2) resulting from intramolecular ArCH~2~–H CH bond activation of the __N__‐heterocy