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Effects of Tetra-n-alkylammonium Ions on the Polarographic Reduction of Methyl p-Chlorophenylpropiolate 1

✍ Scribed by Missan, Seymour R.; Becker, Ernest I.; Meites, Louis

Book ID
126477134
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
498 KB
Volume
83
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Organic electrochemical mechanismsβ€”II. E
Organic electrochemical mechanismsβ€”II. Effects of tetra-n-alkylammonium ions on the polarographic reductions of organic depolarizers
✍ J.P. Petrovich πŸ“‚ Article πŸ“… 1967 πŸ› Elsevier Science 🌐 English βš– 453 KB

The reduction potentials, Ells, of ethyl cinnamate, ethyl crotonate, triphenylcyanopropylphosphonium bromide and cycle-octatetraene have been determined polarographically in dimethylfor-man-ride solvent as a function of the size of the tetra-n-alkylammonium cation used as a supporting electrolyte.

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✍ Kiyoko Takamura; Yumiko Hayakawa πŸ“‚ Article πŸ“… 1971 πŸ› Elsevier Science βš– 378 KB

The effect of proton donors on the electrochemical behavior of aromatic compounds has been studied in recent years 1-3. In general, the aromatic radical anions or dianions are formed initially by the electron-transfer process at the electrode, and the stability of these anions varies depending on th