It has been shown that the adsorption of ions at oxide/electrolyte interface should be treated in terms of adsorption on a heterogeneous solid surface. This is because the adsorption runs via formation of complexes with surface oxygen atoms. Because of the small degree of oxide surface organization,
Effects of surface heterogeneity on ion adsorption by metal oxides and by soils
โ Scribed by Barrow, N. J.; Bruemmer, G. W.; Strauss, R.
- Book ID
- 118047391
- Publisher
- American Chemical Society
- Year
- 1993
- Tongue
- English
- Weight
- 770 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0743-7463
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Spectroscopy has provided a progressive flow of information concerning the binding mechanism(s) of ions and their surface-complex structure. An important challenge in surface complexation models (SCM) is to connect the molecular microscopic reality to macroscopic adsorption phenomena. This is import
## Abstract In this article we study the effect of energetic heterogeneity of a crystalline surface on the adsorption of hydrogen ions (protons) from the liquid phase. In particular, we examine the influence of the shape of the adsorption energy distribution on the equilibrium isotherms of hydrogen