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Effects of solvents on the reaction of 2,2-dimethylpropanesulfinyl chloride with activated zinc

โœ Scribed by Fillmore Freeman; Christos N. Angeletakis

Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
175 KB
Volume
23
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

k@~ao.: Although 2,2-dimethylpropanesulfinyl chloride reacts with zinc in C6H6 or Ccl4 to give the corresponding thiosulfonate as major product, the reaction In C2D10 0, C2H100, and CDSCN affords the corresponding thiosulfinate as the major product. Several aromatic sulfinyl chlorides (4) react with5Cj: in petroleum ether (bp 60ยฐ-800),3'4 or with Zn in ether -0 II Ar-S-Cl

๐Ÿ“œ SIMILAR VOLUMES

Ab initio MO study of the solvent effect
Ab initio MO study of the solvent effect on the SN2 reaction of the trimethylsulfonium cation with chloride anion
โœ Osamu Kikuchi; Yoko Sano; Ohgi Takahashi; Kenji Morihashi ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 524 KB

A recently developed ab initio MO theory including solvent effects has been applied to a typical cation-anion reaction, the SN2 reaction of the trimethylsulfonium cation with the chloride anion. In the gas phase, the trimethylsulfonium and chloride ions are unstabilized, and the reaction is expected