The role played by solvent in the reactions of organic molecules is not well understood. One is often tempted to try to interpret solvent effects on processes in which ions or molecules are formed solely in terms of solvent interactions with an ionic or radical-like transition state to the neglect o
Effects of solvents on free radicals of bitumen and asphaltenes
β Scribed by K.C. Khulbe; R.S. Mann; B.C.-Y. Lu; G. Lamarche; A.-M. Lamarche
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 411 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0378-3820
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Rates and thermodynamic data have been obtained for the reversible self-termination reaction: 2k1 R' + R' G=-D Involving aromatic 2-(4'dimethylaminophenyl)indandione-1,3-y1 (I), 244'diphenylaminophenyl)indandione-1,3-y1 (II), and 2,6 di-tert-butyl-4-(p-phthalylvinyl)-phenoxyl (III) radicals in diffe