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Effects of solvation and ionic association on the electronic absorption spectra of radical-cation salts of substituted triphenylamines

✍ Scribed by V. G. Koshechko; V. A. Krylov; V. D. Pokhodenko

Book ID
112359547
Publisher
Springer
Year
1983
Tongue
English
Weight
417 KB
Volume
18
Category
Article
ISSN
0040-5760

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Zinc(II) complexes of substituted tetraphenylporphyrins, Zn[T(X-P)P], where X = H, p-F, p-Cl, m-Cl, p-CH 3 O, and m-CH 3 O, have been synthesized and characterized. Peripheral substitution shows marked changes in the chemical shifts of the phenyl proton resonances and E 1/2 values of the redox coupl