✦ LIBER ✦

Effects of solution resistance and double layer capacity on the faradaic polarization of an electrochemical cell

✍ Scribed by Gerald F. Thomas; John M. Raycheba

Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 205 KB
Volume: 33
Category: Article
ISSN: 0013-4686
DOI: 10.1016/0013-4686(88)80047-1

No coin nor oath required. For personal study only.

✦ Synopsis

The basis of a method which allows one to investigate the kinetics of corrosion processes in systems exhibiting an uncompensated solution resistance and whose anodic and cathodic reactions have current-voltage behaviors described by the Butler-Volmer relation is presented. Compared to weight-loss measurements or dc techniques, the faradaic distortion method[l, 23 allows for very rapid and reliable assessment of the corrosion rate and Tafel slopes governing the current-voltage characteristics of an electrochemical cell. The method involves perturbing the system with a potentiostatically controlled sinusoidal voltage of fixed angular frequency w and of amplitude U. superimposed on the

📜 SIMILAR VOLUMES

Electric double layer structure in a sur

Electric double layer structure in a surface-inactive electrolyte solution: effect of the stern layer and spatial correlations of solvent polarization

✍ M.A. Vorotyntsev; P.V. Mityushev 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 907 KB

The effect of neutral polymers on the el

The effect of neutral polymers on the electrokinetic potential of cells and other charged particles: II. A model for the effect of adsorbed polymer on the diffuse double layer

✍ D.E Brooks 📂 Article 📅 1973 🏛 Elsevier Science 🌐 English ⚖ 963 KB

The effects of polyethylene glycol (PEG)

The effects of polyethylene glycol (PEG) as an electrolyte additive on the corrosion behavior and electrochemical performances of pure aluminum in an alkaline zincate solution

✍ X. Y. Wang; J. M. Wang; Q. L. Wang; H. B. Shao; J. Q. Zhang 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 German ⚖ 188 KB

## Abstract The effects of zinc oxide and/or polyethylene glycol (PEG) as electrolyte additives on the corrosion and electrochemical performances of pure aluminum in 4.0 M KOH solutions were investigated by means of hydrogen collection, polarization curve, galvanostatic discharge, scanning electron

An electrochemical cell for reduction of

An electrochemical cell for reduction of biochemicals: Its application to the study of the effect of pH and redox potential on the activity of hydrogenases

✍ Victor M. Fernández 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 554 KB

Effects of an intercalating agent on the

Effects of an intercalating agent on the morphology and thermal and flame-retardant properties of low-density polyethylene/layered double hydroxide nanocomposites prepared by melt intercalation

✍ Lei Ye; Qianghua Wu 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 730 KB