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Effects of poly(2-vinylpyridine) as a template on the radical polymerization of methacrylic acid—I. Influence of atactic poly(2-vinylpyridine) concentration

✍ Scribed by J. Smid; Y.Y. Tan; G. Challa

Book ID
107753855
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
437 KB
Volume
19
Category
Article
ISSN
0014-3057

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Effects of poly(2-vinylpyridine) as a te
Effects of poly(2-vinylpyridine) as a template for the radical polymerization of methacrylic acid—II: Influence of initiator concentration
✍ J. Smid; Y.Y. Tan; G. Challa 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 370 KB

The polymerization of methacrylic acid along an atactic poly(2-vinylpyridine) template was studied by varying the initiator concentration, [I]0. The concentrations of monomer and template were 0.4 M, the temperature 30 °. Reaction rates were determined calorimetrically. The experimental results coul

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✍ J. Smid; G.O.R. Alberda van Ekenstein; Y.Y. Tan; G. Challa 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 418 KB

The influence of temperature on the polymerization of methacrylic acid along atactic and isotactic poly(2-vinylpyridine) templates was studied by means of isothermal and scanning (d.s.c.) calorimetric techniques. The overall energy of activation of both template polymerization systems was about 40 k