New structure in the energy distribution of H+ produced by Field ionization of HD is reported. The structure is shoti to result from a field induced pendulum type of motion of HD+ before it dissociates. Effects of associated pair field ionization are discussed. Measurement of the energy distributio
Effects of polarization in the field ionization spectrum of H2O
โ Scribed by R.D. Gilbert; M.S. Child
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 615 KB
- Volume
- 187
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
โฆ Synopsis
Anomalous lines in the ZEKE field-ionization spectrum of Hz0 are explained via a mechanism of energy redistribution between core rotation and the Rydberg electron, mediated by the Rydberg-core-dipole interaction. A quantum defect model of the interaction, involving the coupling of two closed channels, is discussed in relation to predictions ofthe intensities of the observed lines.
Experimental implications of this polarization mechanism are suggested.
๐ SIMILAR VOLUMES
Using high resolution Fourier transform spectra (resolution 0.002 cm 01 ) recorded at the Instituto Ricerca Onde Electromagnetiche Firenze and at the Justus Liebig University Giessen, it has been possible to measure the relative intensities of lines in the far-infrared spectrum of H 2 O 2 in the 25-
The microwave spectrum of the formaldehyde -water complex ( CH 2 O -H 2 O ) has been studied with a pulsedbeam Fourier transform Fabry -Perot cavity spectrometer. Both a-type and b-type transitions were observed for each of the isotopic species studied. To provide additional structural information,