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Effects of Nematic Liquid Crystal Additives on the Performance of Polymer Solar Cells

✍ Scribed by Seonju Jeong; Younghwan Kwon; Byeong-Dae Choi; Giseop Kwak; Yoon Soo Han


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
243 KB
Volume
211
Category
Article
ISSN
1022-1352

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✦ Synopsis


Abstract

Nematic liquid crystals (NLCs), 4‐cyano‐4′‐pentylbiphenyl and 4‐cyano‐4′‐octylbiphenyl, were applied as additives to polymer solar cells with P3HT:PC~61~BM blend films. The incorporation of NLC additives led to a higher absorbance of the blend film, a higher crystallinity of P3HT, closer P3HT chains, larger PC~61~BM domains and enhanced hole/electron mobilities even without post‐thermal annealing. The non‐annealed PSC with 4 wt.‐% 8CB additives showed an increase in all parameters, resulting in a power conversion efficiency of 3.72% compared to 2.14% of the reference device without NLC additives. magnified image


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