Effects of nanoclay on the properties of cardanol-modified-resol-epoxy-novolac composite material
β Scribed by Le Huong Nguyen; Dac Thanh Nguyen; Thai Ha La; Kim Xuyen Phan; Thi Thanh Thao Nguyen; Huu Nieu Nguyen
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 188 KB
- Volume
- 103
- Category
- Article
- ISSN
- 0021-8995
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β¦ Synopsis
Abstract
A nanocomposite based on nanoclay and resol that was modified with cardanol, a natural alkyl phenol, shows improvement for the glassβfiberβreinforced epoxyβcomposite system. Dispersion of the nanocomposite was investigated by Xβray, showing good results obtained by the in situ polymerization method. The mechanical properties of the final composites were improved by doping a 6 wt% of nanoclay in cardanolβmodifiedβresol (CMR) into the epoxy matrix. The results show that a 15 wt% of CMR in epoxy is a most suitable ratio. Using polyamide as a curing agent instead of other traditional systems, such as anhydrides or amines for epoxy resin, overcame important limitations, further allowing for improved processability. The overall composite performance was enhanced. Additionally, the thermal stability of the system was investigated by thermal gravimetric analysis. Β© 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3238β3242, 2007
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Three di β erent epoxy resins, based on the diglycidylether of bisphenol A (DGEBA), triglycidyl-p-aminophenol (TGPAP) and tetraglycidyldiaminodiphenylmethane (TGDDM), which are di-, tri-and tetrafunctional, respectively, were mixed in varying proportions and cured with both 3,3@-diaminodiphenylsulpho