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Effects of molecular asymmetry on 13C chemical shifts in some O- and N-glycidyl compounds

✍ Scribed by B. Everatt; A. H. Haines; B. P. Stark

Publisher
John Wiley and Sons
Year
1976
Tongue
English
Weight
267 KB
Volume
8
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

In the ^13^C{^1^H} n.m.r. spectra of certain organic compounds containing two or three glycidyl (2,3‐epoxyprop‐1‐yl) groups, chemical shift nonequivalence has been observed, between diastereoisomers, for chemically similar carbon atoms in the glycidyl groups. Nonequivalence was only apparent when the glycidyl groups were linked through a single atom. In three derivatives of diglycidylaminobenzene, ^13^C chemical shift nonequivalence was also observed for aromatic carbon atoms ortho to the nitrogen substituent.

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