Effects of Intramolecular Hydrogen Bonding on the Ionization Energies of Proline
โ Scribed by Shan Xi Tian; Jinlong Yang
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 992 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Ab initio 3CF and SCP Cl caJcuJatjons ~4th Zhe STO-3C basis set have been pcrformcd in this study of the effect of jntramolccubr hydrogen bonding on n orbital cncrgjcs and n -r I?\* transition encrgiw in ,&hydroxyacrofcin. In the hydrogen bonded C, form, the n orbital is stabWed and the n -+ s\* tnn
Measurements were made in CCI, of the formation constant K,, of the 1 : l hydrogen-bonded complexes between the reference donor 4-fluorophenol and the intramolecular hydrogen-bonded systems I (one lone pair on heteroatom Y, one intramolecular hydrogen bond: 8-hydroxyquinaldine and 2-(2-hydroxyphenyl