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Effects of hydroxide ion, salts and temperature on the hydrolytic cleavage of ionized N-hydroxyphthalimide (NHPH) in the presence of cationic micelles

✍ Scribed by M. Niyaz Khan


Book ID
118606071
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
604 KB
Volume
127
Category
Article
ISSN
0927-7757

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Pseudo first-order rate constants (kohl) for methanolysis of ionized phenyl salicylate (PS-) show a decrease of 3-5-fold with increase in CH,CN content from 2 to 60 or 70% (v/v) in mixed aqueous solvents containing 0.01 mol dm-3 LiOH and a constant content of CH30H. At 0.01 moldm-' KOH, the rate con