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Effects of heteroatoms on 1,2-rearrangements of 3-membered ring carbenes

โœ Scribed by Wang Bing-Ze; Liu Jin-Ting; Li Xiao-Fang; Deng Cong-Hao

Book ID
112058920
Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
308 KB
Volume
8
Category
Article
ISSN
0256-7660

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The (Z)-(iodovinyl)oxetane 12 was prepared from d-glucose and the acyclic analog 18 was obtained from d-mannitol. Following the generation of their lithium derivatives by halogen-metal exchange, coupling to the enantiopure vinylsubstituted norbornanones 20, 23, and 29 proceeded exclusively via endo