The influence of functional group interactions on the bimolecular and dissociation reactions of diols were examined in a quadrupole ion trap mass spectrometer. Reactions of dimethyl ether ions with diols resulted in formation of (M + H)(+) ions and (M + 13)(+) ions (by net methyne addition). The pro
Effects of functional group interactions on the gas-phase methylation and dissociation of acids and esters
β Scribed by John J. Isbell; Jennifer S. Brodbelt
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 764 KB
- Volume
- 7
- Category
- Article
- ISSN
- 1044-0305
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The dissociation reactions of protonated amino alcohols were examined in a quadrupole ion trap mass spectrometer. Multi-stage collision-induced dissociation techniques were used to characterize the ions and their fragments and to assist in the determination of the dissociation mechanisms. In additio
## Abstract A computational investigation of the optical rotatory power of __cis__ and __trans__ 2βmethylβ5βoxoβtetrahydroβ3βfurancarboxylic acids and the corresponding methyl and ethyl esters is presented. Solvent effects on both the conformational space and the rotatory power are analyzed by comp