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Effects of First-Row Substituents on Silicon−Phosphorus Triple Bonds

✍ Scribed by Lai, Chin-Hung; Su, Ming-Der; Chu, San-Yan


Book ID
125897952
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
43 KB
Volume
41
Category
Article
ISSN
0020-1669

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Substituent effect on relative stabiliti
✍ Ya-Hui Hu; Ming-Der Su 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 235 KB

The unimolecular rearrangement of XSnBP (X ¼ H, Li, BeH, BH 2 , CH 3 , NH 2 , OH, and F) to Sn@PX is considered using B3LYP and QCISD calculations. The theoretical findings suggest that the doubly bonded Sn@PX molecule is intrinsically more stable than the triply bonded XSnBP species, regardless of