The quadrupolar and dipolar interactions of spins during the radio frequency (RF) pulses are considered. It is shown that due to these interactions the two-pulse echo signal is observed at the shifted time t, = T + t,/2 (t, = width of the first RF pulse, 7 = time interval between the pulses).
Effects of finite pulse width on free induction decay
โ Scribed by N.A. Sergeev
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 428 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0926-2040
No coin nor oath required. For personal study only.
โฆ Synopsis
The shape of the free induction decay for the case in which the amplitude B, (B, = 0,/y) of the RF pulse is comparable with local magnetic fields at sites of the nuclei is considered. It is shown that the shape of the FID G(r + T) (where T is the width of a RF pulse, t is the time after a RF pulse) depends on the shape of the FID G,(t) following a hard, delta function RF pulse and on the shape of the function Fe(r), which describes the evolution of the longitudinal nuclear magnetization M, under the effect of the hamiltonian (Ho -o,l,), where H, is the interaction hamiltonian of the nuclear spin system.
Calculations of Fe (7) and G(t + T) for different interaction hamiltonians H, are presented.
๐ SIMILAR VOLUMES