Effects of fiber surface chemistry and roughness on interfacial structures of electrospun fiber reinforced epoxy composite films

✍ Scribed by Huaqiang Liao; Yiqiong Wu; Meiyu Wu; Haiqing Liu

• Publisher: Society for Plastic Engineers
• Year: 2011
• Tongue: English
• Weight: 828 KB
• Volume: 32
• Category: Article
• ISSN: 0272-8397
• DOI: 10.1002/pc.21107

✦ Synopsis

Abstract

This work reported the effect of surface chemistry and roughness of electrospun fibers on fiber/matrix interfacial structures and the resultant macroscopical properties of composite films. Three types of fibrous mats composed of ultrafine fibers, that is, cellulose acetate (CANM), polyurethane (PUNM), and cellulose acetate/polyurethane composite (CAPUNM) were fabricated through electrospinning. CA fiber surfaces were rough with many hydroxyl groups; PU fiber surfaces were smooth, whereas CAPU composite fibers exhibited cocontiuous structure with rough surfaces. The fiber‐reinforced epoxy composite films were prepared by the solution impregnation method. The fractured surfaces of the composites were analyzed by scanning electron microscopy. Severe interfacial debonding and fiber pullouts were observed for PUNM/epoxy composites, while strong interfacial adhesion was formed for CANM/epoxy and CAPUNM/epoxy composites. The interfacial structure played important roles in the visible light transmittance of the composite films. For example, CANM/epoxy films showed the best optical property, whereas PUNM/epoxy films displayed the poorest light transmitting property and were translucent. The interfacial structure also affected the mechanical properties of the composites. The mechanical strength of fibrous mats followed an increasing order of CANM < CAPUNM < PUNM, but the mechanical strength of the composite films was in a reverse order, that is, CANM/epoxy > CAPUNM/epoxy > PUNM/epoxy. POLYM. COMPOS., 2011. © 2011 Society of Plastics Engineers