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Effects of diffusion on long-range electron transfer

✍ Scribed by A.M. Kuznetsov; J. Ulstrup

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 484 KB
Volume: 97
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)80009-8

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✦ Synopsis

The competition between diffusive hops and direct tunnelling of solvated electrons to scavenger molecules in solid glasses has been discussed in the literature_ We have considered these two reaction paths in terms of stationary kinetic diffusion equations and multiphonon electron-transfer rate theory, and for coupling of the solvated electron to a broad continuum of nuclear modes. Diffusion can only be expected to be important for less polar glasses.

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