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Effects of Cyclopentadienyl and Phosphine Ligands on the Basicities and Nucleophilicities of Cp‘Ir(CO)(PR 3 ) Complexes †

✍ Scribed by Wang, Dongmei; Angelici, Robert J.

Book ID
127247167
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
438 KB
Volume
35
Category
Article
ISSN
0020-1669

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✍ Helmut Fischer; Kerstin Weißenbach; Christoph Karl; Armin Geyer 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 631 KB

2 Mn=C(OR\*)Ph] (4aϪe) phanes afforded (S Mn )-[Cp(CO)(PR 3 )Mn=C(OR\*)Ph] [PR 3 = P(OPh) 3 (8), P(OMe) 3 (9), P(OMe) 2 Ph (10), P(OMe)Ph 2 (11), were prepared by reaction of [Cp(CO) 2 Mn=C(OAc)Ph] (2) with HOR\* [HOR\* = 1,2:3,4-di-O-isopropylidene-D-galacto-PPh 3 (12), P(C 6 H 4 Cl-p) 3 ( )] with