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Effects of conformation and solvent polarity on intramolecular charge transfer: a picosecond laser study

โœ Scribed by M.K. Crawford; Ying Wang; K.B. Eisenthal


Book ID
107732743
Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
394 KB
Volume
79
Category
Article
ISSN
0009-2614

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## Intramolecular charge transfer and heteroexcimer formation processes in the excited state of (CH3)2N-C6&-(CHl)ncl-pyretiyi) <pn) have been investigated by means of picosecond laser photolysis. It has been demonstrated directly that photoinduced charge transfer produces at first a heteroexcimer

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The singlet to triplet intersystem crossing rate (&) for a series of diphenylcarbene derivatives is found to be a sensitive function of the energy splitting (AEsT), which in turn depends on the solvent polarity and on the structure ofthe carbene. A turn-over in the dependence of ksr on AEsT is found