Effects of conformation and solvent polarity on intramolecular charge transfer: a picosecond laser study
โ Scribed by M.K. Crawford; Ying Wang; K.B. Eisenthal
- Book ID
- 107732743
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 394 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0009-2614
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๐ SIMILAR VOLUMES
## Intramolecular charge transfer and heteroexcimer formation processes in the excited state of (CH3)2N-C6&-(CHl)ncl-pyretiyi) <pn) have been investigated by means of picosecond laser photolysis. It has been demonstrated directly that photoinduced charge transfer produces at first a heteroexcimer
The singlet to triplet intersystem crossing rate (&) for a series of diphenylcarbene derivatives is found to be a sensitive function of the energy splitting (AEsT), which in turn depends on the solvent polarity and on the structure ofthe carbene. A turn-over in the dependence of ksr on AEsT is found