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Effects of chloride on the adsorption, orientation and polymerization of 1-octyne-3-ol on iron

✍ Scribed by V. Jovancicevic; B. Yang; J.O'M. Bockris

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 211 KB
Volume: 32
Category: Article
ISSN: 0013-4686
DOI: 10.1016/0013-4686(87)90003-x

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✦ Synopsis

Chloride ions exhibit a pronounced effect on the adsorption and reorientation of l-octyne-3-01 on iron from acid solutions. The adsorption inhibition of octynol by Cl-gives rise to thinner adsorption layers suggesting a strong competitive adsoprtion mechanism. The orientational transition is shifted toward longer times with a stronger adsorption of octynol in the upright orientation. The rate of growth of the polymer layers is unaffected by the presence of c1-ions.

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